Introduction to Geology- Physics 258 - 02: Foley

GeoInfo Sheet - Rocks & Minerals

Atomic Theory:

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Atoms: Nucleus(Protons, Neutrons), Electrons;

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Elements: all one type of atom (Gold, Carbon, Uranium, etc), Periodic Table

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Properties: Electron Structure (configuration)

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Chemical (electron) Bonds

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Covalent Bonding - Very strong, shares the outer shell electrons.  (Diamond)

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Ionic Bonding - One atom loses a charge (e-) and another gains one, medium strength.  (NaCl)

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Van Der Waals Forces - Weakest bond, results from a slight polarization in the atoms.

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Metallic Bonding - (a form of covalent bonding) – Free electrons; good thermal and electrical conductors.

Minerals

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Homogeneous

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Naturally Occurring

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Solid

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Inorganic

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“Fixed” or limited composition (chemical composition) SiO2 (quartz), NaCl(salt), Al2O3(ruby)

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Crystal Lattice Structure

Rock: assemblage of one or more minerals.  Rocks may vary considerably in mineral composition.

Major Rock Groups:

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Igneous rocks are formed by the cooling of magma (below the surface) or lava (above the surface).

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Sedimentary rocks are made up of particles derived from the breakdown of pre-existing rocks.  Lithification is the process that changes unconsolidated deposits into rock.

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Metamorphic rocks have changed their form due to exposure to pressure, heat, and/or chemically active fluids.

The Rock Cycle describes the relationship between these three categories of rocks.

 

Minerals

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Over 3,000 different minerals that have been classified.  Some minerals are much more abundant than others.
(
It is extraordinary that the total number of minerals is a mere 3700, or so; compared with more than ten million different chemical compounds. There are even four million species of insects, of which 300,000 are beetles. This fact prompted J B S Haldane to remark that he didn't know much about the nature of God, except that He was "inordinately fond of beetles"! )

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Just 10 elements make up 99% (by weight) of the Earth's crust.  These are O, Si, Al, Fe, Ca, Na, K, Mg, Ti, H.

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Most (74.3%) of the minerals in the Earth's crust contain Oxygen (O) and Silicon (Si).

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Silicate mineral family (minerals having the ion SiO4) compose 90% of all rock forming minerals.

Minerals identification by:

Traditional: examining the physical properties of the mineral.

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Crystal Form (or Habit) is the external shape produced by a minerals internal crystalline structure.

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Color is a property that describes itself.  It is the color of a mineral.  Most geologist consider this property a weak differentiator among minerals.  But a few minerals will possess a very "striking" color.

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Streak is the color of a mineral in a finely powdered form.  This is usually determined by running the mineral across a piece of unglazed porcelain called a streak plate (or just unglazed white tile found at the hardware store).

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Luster is the appearance or "quality" of light reflected from a minerals surface.  It is often divided into metallic and non-metallic luster (silky, glassy, satiny, resinous, pearly, etc).

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Striations are parallel, threadlike lines or narrow bands running across crystal faces or cleavage surfaces.

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Cleavage is the tendency of a mineral to break in certain preferred directions along smooth planes.

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Twinning is the intergrowth of two or more single crystals of the same mineral with different geometric orientations.

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Hardness is determined by the relative ease or difficulty with which one mineral can scratch another. Using known mineral samples to test the hardness of an unknown is common practice. [Mohs Hardness Scale]

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Specific Gravity is, essentially, the mineral’s density when compared to the density of water.

 Modern Methods

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X-ray diffraction (determines crystal structure)

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Mass spectrometry (determines composition)

Additional Properties:

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Magnetic (ferromagnetism) - is it attracted to a permanent magnet?

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Fluorescence - becomes luminescent during exposure to UV or IR light.

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Phosphorescence - stays luminescent even after exposure to UV or IR light.

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Pyroelectricity - temperature changes will cause charges to build up on the surface.

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Piezoelectricity - pressure changes will cause charges to build up on the surface.

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Solubility - does it effervesce in dilute HCl acid?  (Carbonate minerals usually do effervesce.)

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Fusibility - can an intense heat (flame) cause two samples to fuse together? 

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Fracture - minerals can break in distinctive ways that are different than cleavage.

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Tenacity - resistance to breaking when exposed to mechanical stress.

 Polymorphs: Two different minerals having same chemical composition [graphite, diamond]

 Crystal Formation:

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Solidification of a melt (water > ice)

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Precipitation from a saturated solution (geode)

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Solid-state diffusion (very slow)

 Crystal Type:

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Euhedral: uninhibited crystal growth, well formed crystal faces

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Anhedral: restricted crystal growth, truncated crystal faces

 Crystal Destruction:

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Melting

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Dissolving

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Other Chemical Reactions (rust/oxidation)

Mineral Groupings (or "Families")

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Native Metals/Elements – Copper, Gold, Silver, Diamond, Sulfur

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Silicates – [X+SiO4 ] MgSiO4 (Olivine), SiO2 (Quartz)

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Oxides – [X +O, O2, O3, etc] Fe3O4 (Magnetite), Fe2O3 (Hematite), Al2O3 (Ruby/Corundum)

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Sulfides – [X + S, S2, S3, etc] PbS (Galena), FeS2 (Pyrite)

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Sulfates – [X + SO4] CaSO4 (Gypsum)

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Halides – [X + Cl, I, Br, F, Halogen] NaCl (Rock Salt), CaF2 (Fluorite)

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Carbonates – [X + CO3] CaCO3 (Calcite), CaMg(CO3)2 (Dolomite)

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Phosphates – [X + PO4] Ca5(PO4)3(OH,F,Cl) (Apatite)

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Hydroxides – [X + H2O] Al2O3 (2H2O) (Bauxite)

 Mineral deposits are usually divided into metallic and nonmetallic.

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Metallic - Fe, Al, Chromium, Tin, Uranium, Silver, Mercury, Gold

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Nonmetallic - Salt, Building Stones (or Dimension Stones), Sand and Gravel, Phosphorus, Sulfur

If a mineral deposit is economically worthwhile to mine, then it is called an ore. Ways to extract ore from the ground:

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Open-pit or "Strip" mining is carried out at the surface and digs down removing the overlaying material.

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Underground mining involves tunneling into the earth and removing material.  Usually consists of mine shafts down to a horizontal layer of ore being removed.

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Placer mining usually involves the separation of valuable metals or nonmetals from unconsolidated material near the surface.  Bauxite, the principle ore of aluminum, is often extracted this way.

Carrot is a vegetable. 
Karat refers to the purity of gold.   24 karat is 100 % gold but 14 karat is 14/24 (58.3%) gold with an alloy. 
Carat
is a measure of the mass of a precious gem (1 carat = 0.2 grams, or 5 carat = 1 gram).